A high-pressure crystallographic and magnetic study of Na5[Mn(l-tart)2]·12H2O (l-tart = l-tartrate).
نویسندگان
چکیده
The crystal structure and magnetic properties of the compound Na5[Mn(l-tart)2]·12H2O (1, l-tart = l-tartrate) have been investigated over the pressure range 0.34-3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na(+) ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 44 42 شماره
صفحات -
تاریخ انتشار 2015